3-Methylcyclohexenone. NSC 43632. Address: P.O. UNII-786Y352V9X. Details of the supplier of the safety data sheet Emergency Telephone Number CHEMTRECÒ, Inside the USA: 800-424-9300 CHEMTRECÒ, Outside the USA: 001-703-527-3887 2. 1.3 Details of the supplier of the safety data sheet Company Breckland Scientific Supplies Ltd Address Antom Court, Tollgate Drive, Stafford, ST16 3AF Web www.brecklandscientific.co.uk Telephone 01785 227 227 Fax 01785 227 444 Email msds@brecklandscientific.co.uk Emergency telephone 08:30 … 3-Methyl-2-cyclohexene-1-one. Molecular Weight 170.32 . Stability and Reactivity Stability: Stable at room temperature in sealed containers. EPA Pesticide Chemical Code 219700. stream CHEBI:88428. Cyclohexene Created by Global Safety Management, 1-813-435-5161 - www.GSMSDS.com If medical advice is needed, have product container or label at hand. <> Now wash the cyclohexene (where is it?) nutty cyclohexenone. Material Safety Data Sheet Cyclohexene, 99% ACC# 00500 Section 1 - Chemical Product and Company Identification MSDS Name: Cyclohexene, 99% Catalog Numbers: AC154840000, AC154840010, AC154840025, AC154842500, AC154845000 Synonyms: Benzenetetrahydride 1,2,3,4-Tetrahydrobenzene Safety Data Sheet (SDS) SDS #: 292. Box 219, Batavia, IL 60510 (800) 452-1261 Chemtrec Emergency Phone Number: (800) 424-9692 Signal Word DANGER. EC Number 229-675-1. EYES: Irritating to eyes. Safety Data Sheet Cyclohexanone Version 1.1 Revision Date: 05/12/2015 MSDS Number: 100000004919 4 / 18 Cyclohexanone ance. Brookfield, Wisconsin 53045 262-792-1450 262-792-8721 Fax <> 4-Vinyl-1-cyclohexene, stabilized Revision Date 18-Jan-2018 Decomposition Temperature No information available Viscosity 0.7 mPa s at 20 °C Molecular Formula C8 H12 Molecular Weight 108.18 10. Safety Data Sheet according to 29CFR1910/1200 and GHS Rev. Material Safety Data Sheet Cyclohexanol ACC# 00499 Section 1 - Chemical Product and Company Identification MSDS Name: Cyclohexanol Catalog Numbers: AC147680000, AC147680010, AC147680025, AC147680050, AC147680200, AC147685000, S79991, C558-500 Linear Formula C 6 H 9 OSi(CH 3) 3. ?��������� �\h(��.^���Lma�bjon�S�N*ejN��+��b!�ݖ���h�A���% �o�4}�,�$�Q�E�n�J �R�� ����" �x�K'R��N#˒�k�E5R4��q���/W�D�S9��4�p+������-u5p�e*a��.��R�+��?� o.�H��Z��ɝ��Cط�#t��g�ӛ�=!dq����Y���͆h��88_��i� &C��b�9���f��ql�N�{f��Mj# If inhaled : Consult a physician after significant exposure. Symptoms include itching, burning, redness and tearing. H304 May be fatal if swallowed and enters airways. Revision Date: March 25, 2014. endobj NACRES NA.22 MDL number MFCD00001541. This cycloalkene is a colorless liquid with a sharp smell. Read label before use. %���� It is employed as a precursor to caprolactam, adipic acid, maleic acid, dicyclohexyladipate and cyclohexeneoxide. endstream S^õ¾»è°s²ß{_)Œ/)Ï|5¸£ƒ vRŒŸáHGÇmŠPûÁg…9ýÂŽ—ù@,;ëš½D÷Nl=ƒÃ ÝQŒÏ˜¹Å™šO #K¶Ä¬;ûËÇõF.¯8Ífåü .9ù-¿ñι~ZoÇæÝ á¬ñ‡˜ÔÊè­¾F.ñh>©j&©žOӕϠ“”¤mç}íýQ[x¾0"åÛÀOæäZcyÔ M ®æà.ßUñѪRЄÔ=’ÿŽY³Ç&0æüYUùŸ+«ˆ9.áhF€Úž¨ŠMÛ¨ ýÀ*M¾>_û¢dµ&$jl #½>6¡UFü®u§ÞùْlÑ1HJ½$˜Ëz×ì1Ì=–£ãbFÀ”‘÷‡øuOÅäž ƒE¶h’Zúظ“õ.ۏ×óæ†Ä¹×œ;f ´¬"+‡ºO}˜®)[-,v‰ä݄üò¼i¢^RZ è3‹›w‘uޖ½¡9Tf®Õ½@çÿ%|C–á,´iαBÓ²“8*ȱoå8¸±ãsx"ëÀŠ&eÑgrL&µâˆ6(±eÝÔ»Ô@«íë£Mâ@HÛ~ö¹ˆ¹Ä—ßٝlVÄTN—‰VÙ¦ "÷SF÷Š"HɘµÏÿ¾Z²nBýM×záÉNŠ\ÎÉâãv5â‰áÁåÄäü-ç°ôº>HÖz :•Mð-$yèAœÇYXY²j;-Ë'¹ ;Y ½w½ù՜]Ó±C-]ÿÍ=] -104 °C Alfa Aesar-104 °C OU Chemical Safety Data (No longer updated) More details-103.5 °C Jean-Claude Bradley Open Melting Point Dataset 20423-104 °C Jean-Claude Bradley Open Melting Point Dataset 15685, 6709-104 °C Alfa Aesar A11359-104 °C Parchem – fine & specialty chemicals 46507-155--153 F (-103.8889--102.7778 °C) Wikidata Q413328-154 F (-103.3333 °C) Wikidata Q413328 ���U�� Cyclohexane CAS No 110-82-7 MATERIAL SAFETY DATA SHEET SDS/MSDS Signal word Danger Hazard statement(s) H225 Highly flammable liquid and vapour. Cyclohexene is not very stable upon long term storage with exposure to light and air because it forms peroxides. )����[Y�:������c��& ���Ҁ�{�' �v��~m�SC��T@w���HCޑ1I�� �_� �KZnMC�3����|A|����;�D��d���;;���+N �/?Gx�;�O�Ip{��9���Jm�*�f/����41�uX���Վr��C�V�eF����@�],2�c�3� ��t����5��j�cF@������l6d���NA���fk49G4���v�. In the presence of various catalysts (such as acids) or initiators, may undergo exothermic addition polymerization reactions. MATERIAL SAFETY DATA SHEET (MSDS) www.lobachemie.com Version: 1 25/05/2016 1/9 CYCLOHEXENE FOR SYNTHESIS MSDS CAS No: 110-83-8 MSDS SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. 's�'���>7TD�I)^��j�ќ�8ȼ�?b$�ȸ��,xv~'z��N��9�ZZ��%�-�7'��9�Ȱ��*���p(�M��WT����>���3��������S�/?5y�� v��O[m�d�d�>c:��2���Y�st[K2�y$�WL��;P�օ����m�[�� LJ��U?Q*0φ����F�o�-j�� ]�w�W�'R��$9 q�K��7~��;�0 {���zpz������`�ͼO�q���t��)ytM���4ɶ �L�!��x�;-q���[���� W�Cϑ�*��:��D��ղ�;�VN�+�T��P���fzs�.���Z�_�pG�������DU���#�D�N�����&IZ�i_��Cl� ��]`�V����a���%�AWd�d`�g]���P]\?��H5�2� 9��R� Conditions to Avoid Excess heat. PubChem Substance ID 24848686. 3 Effective date : 10.24.2014 Page 2 of 8 Ethyl Ether, Anhydrous, ACS Created by Global Safety Management, 1-813-435-5161 - www.GSMSDS.com If medical advice is needed, have product container or label at hand. BRN 1560601. ghl.PD_Mitscher_leg0.699. Hydrite Chemical Co. 300 N. Patrick Blvd. /Contents 4 0 R>> It can also undergo hydrogen peroxide oxidation in the presence of peroxytungstate-oxalic acid complex catalyst to form adipic acid. 5 0 obj PRODUCT AND COMPANY IDENTIFICATION Product name : Cyclohexane Product Number : 227048 Brand : Sigma-Aldrich Supplier : Sigma-Aldrich 3050 Spruce Street SAINT LOUIS MO 63103 USA Telephone : +1 800-325-5832 Fax : +1 800-325-5052 Emergency Phone # (For Ùx£4¹¹æZ¢zˆŽ×|‹Ÿ0‚9µ ÎÉ°•ÖÚµ,4tß=¯˜&. a�UPS���_�2�7��3B[���ow:�7u��"�Uc�h%���E�~|��M�͝�ST���p���K�{��d?������W�t�reɩ�dE�����d�ޝ�6�Qh$X��v깄T�ޠ�b�l~ ±K~AVxóO@'ZMِ¥ó#ü Keep out of reach of children. *Please select more than one item to compare <> Safety Data Sheet according to 29CFR1910/1200 and GHS Rev. 3-Methyl-2-cyclohexen-1-one, 98%. Beilstein/REAXYS Number 1859394 . 3-methyl-cyclohex-2-en-1-one. Safety Data Sheet according to 29CFR1910/1200 and GHS Rev. /Contents 6 0 R>> Page 5 of 7 MSDS ± Cyclohexane Vapor Pressure (mm Hg) : 95 @ 20C (68F) Evaporation Rate (BuAc=1): 2.6 (Ether = 1) 10. Stability and reactivity Reactive Hazard None known, based on information available Stability Stable under normal conditions. MSDS Creation Date: 12/12/1997 Revision #6 Date: 10/03/2005 The information above is believed to be accurate and represents the best information currently available to us. Hazard(s) identification Classification This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200) Label Elements Signal Word Danger � sH$Ν�釨���m,XKd%�աyy�J��pn9��S�� �ȉ��N_�+O)8�C�vt^ZGAr ��&��l�@L'/������\����$�/�GjEz ��1��P�2�׸��.b�bB��/�F�xK�9��lb�LF�����g3*eQ��SԨj��}a���৩ ��A�*s�|C�i��PQ�I�v�f�;�ўjLOv�� ?�o"��F\ɇ��ҌD�T]�Ҭ3�p�L�t�o���H�&9����5�^�~�P���(R]+��Z�0���x�t�:]����l�T���;�"G��d`�!�m���吏/~�d���%|�@U���=݋$&*(SX�r�����j��Y�e����5ZM����"��ҊL뼞S�!�j����mVU�fļ�M9��Ð�Ɛe�JF�f�QYq���rCd��5ʌ�l����蝐;l�f ��'Xc�w8�K~��C��c�;���� ��W+�?g�]�)By���r���T���aP$�N���XĄbL�s��! Repeated or extended contact may cause erythema (reddening of the skin) or dermatitis, resulting from a defatting action on tissue. Box 219 Batavia, IL 60510: Phone: 800-452-1261: Fax: 866-452-1436: Email: flinn@flinnsci.com %PDF-1.4 4 0 obj *Please select more than one item to compare MATERIAL SAFETY DATA SHEET Cyclohexane MSDS Number: BDH-160 Page 2 of 9 POTENTIAL HEALTH HAZARDS SKIN: Irritating to skin. 1-(Trimethylsiloxy) cyclohexene 99% Synonym: 1-Cyclohexenyloxytrimethylsilane, Cyclohexanone enol trimethylsilyl ether CAS Number 6651-36-1. T��ud�m_ �,�"+���F��l4����Y~ Chemsrc provides 2-Methylcyclohexanol(CAS#:583-59-5) MSDS, density, melting point, boiling point, structure, formula, molecular weight etc. Run off the aqueous layer. EINECS 214-769-7. CYCLOHEXENE may react vigorously with strong oxidizing agents. Compare Products: Select up to 4 products. (Make sure that it is aqueous by adding a drop of water to the flask in which you have collected it!!) Compare Products: Select up to 4 products. The two layers are shaken together briefly, whereupon spontaneous heating occurs. SECTION 1 — CHEMICAL PRODUCT AND COMPANY IDENTIFICATION. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. In case of skin contact : If on skin, rinse well with water. The structural formula for Cyclohexene is: WHAT IS CYCLOHEXENE? @��|���ܴN��Y����z�t� D XX�[�OԲ\V��^�o��YO��n?T=!6NY�\s�0M2����� Z.t�Iw}B���; �E��:�����P'��5�� F`��&���B\Q�O��>��ץ�7�p�!B^6�qD�H�Z3h���|��c�l�zC�yŋk�BEm̦��a�\9IuL&t)��~�x�B&��:˂O�T �1���m��d�G�FJN�ї[��ݮ'o��=#���jL�BXN)U[X�MV�J� 1��PU|k�+�!$��v�#���5���/&�H[5�(�)�h�͸�(��L8��+*�9 |���9ޣ �=����J8ͫE]��\M�I�a�oc=$#g�Z��m��]�� Y�x�4Q�����64�R�Z�s�4�%͟�2c*xs�>- �7����4H�$6�|��|�Bq#:����.�vt��DM��K��ˊ�1�O���sN�4��� k m Wh̐=W����{���b�&�,��hLng[�l���(»��R�]��L���LD��9b?|Z�2�vtz����z�ˊҩ!��5)W@C�ϵ��� /�d��NG@��YQ+_v��j�`��ug����..'[#�|Z`. Cyclohexene has been used in the green synthesis of cyclohexene oxide via hydrogen peroxide epoxidation in glycerol-based solvents using bis[3,5-bis(trifluoromethyl)-diphenyl] diselenide as a precatalyst. 3-methylcyclohex-2-enone. Material Safety Data Sheet Version 3.0 Revision Date 08/22/2008 Print Date 09/13/2011 1. MFCD00001581. Allow the layers to separat and run off the aqueous layer. The mixture becomes homogeneous at 65–70°, this temperature being maintained for 2 hours on a steam bath. 6 0 obj Material Safety Data Sheet Version 5.1 Revision Date 05/17/2013 Print Date 02/27/2014 1. tHk©âî°û:#;ì.^M1jŽk¾˜Bôœb@mß@ׯ£óq9Í©bc¯½h›þGÌÀíV®í¤šv“¼þ{¿ßS3öªÀÆQuØáCU±Qc!æý‡ç[›jàŸÿ³à'&_Ll’ÐzÐ눘¨ê±JאYm˜“ã Search results for cyclohexene oxide at Sigma-Aldrich. Hazardous Decomposition Products: Carbon dioxide and carbon monoxide may form when heated to decomposition. Do not leave the victim unattended. If unconscious place in recovery position and seek medical advice. 3 0 obj Cyclohexene is one of the chemical products on offer here at Chemoxy.. stream CAS 5989-27-5 20324-33-8 26027-38-3 BIOACT AE-O cyclohexene, 1-methyl-4-(1-methylethenyl)-, (r)-; 2-propanol, glycols, polyethylene, mono(p-nonylphenyl) ether; (nonyl msds toxicity property Search Keep out of reach of children. 0\�|~���c�=�w(:"�O)/����۰k�ᵫ�YW�Ыײ�?M5g�ռ�9V��X ���Ra��jcG+ٻ[���}�i���h�j�`J�dӗ��u_�����gE�8gt�|����r!�dq}���m�a�'%)�ch⼟�m��x)$ �?�1�Ղ�an4���0�uPiO76�ݙ�.yŋt��$8�R��G����~�!瓉.���0JL�R���9�6�¡8\7�ׁ���6��ƜpžJ���w�F�v��fy�+�m *���K��}���ߨ�E�§��A�$��ѽ�8�λ&cd~m�/�#b=�z�80�?�/$�Z~g|%�%)Wn\'�.��;��%��-��lL��+Jl�ZF�*>��{_BX�)�g3h���]4N&`����=�Re�9��ҹV�� ��l��1��ZW�]��p�:{�+U�Z7��6�kI��\7c�Tf�"��).�a0'8^ϊ�^c��<�چ��:٢~?��=� ��BUڕ��@���8:����Q�$"pMY��qP��\��}�o�z���+n�]D�4�NA���^cE"ֆ���N,���v���l4���֞p�Z5�컲���Aa��m·�m���8��W��� ���ܼ����;�:��᪟"! 786Y352V9X. <> m���D��v�����D�=�� ��f%h��������ʜMk_�n`� +��$7��R�����*c&��Χ����.�7:����Vv~�H�І���D`��z�]WM�����A[o�'�C�$��R�\��8�z��l���\�+��-9�"�uZ�Ai��b��\ A���:�_twu�M�bV Yu3j���B���Uă�!�gW~�^/Z����[@ �ْ�ն�����\׃�m2D#]��3���?��O���hWlALsނ-���¿��w�8�Nj�!K�^Jթ�&��B* ���erQ4XK�Fѧ�>%ӗ�tE�]��Ga��)��ċ�R����[R�y��>�C4˔K\K�����+�`5U�j���w�ǚ.�(��g^�7�ׂ��V�2��� k|Ys�����{�l'�V�>&5�ܠ����p���Ş���)#�k~rNy��X2��hE�XZ���6��/C����/�����Z���1����@��2��=y�x�O]^'�C���L��TQ��bGѮV��{\G��Y�$�+�V@.�ޟ�#��Ȩ�I�����P�Bz�."?�8��\�szIb>D�ol��ho��ݥ������t3;&���G(r$S8�"���Φ`=��ϧ�����ރ�L]��y�,��Zc�W@9`�)bp,����? It is used as an intermediate for the production of cyclohexanol and cyclohexeneoxide. Cyclohexene (density 0.81 g cm-3) will separate out from the water. H315 Causes skin irritation. Qq�b=}!�5�Θ�Z��� ��T^�~}������?��C��~��M�T r(���^R�Ɂ��t��u�M��� 9�Ũ��kz��UZ�����H�7�N3J��������yF�ޒ �U�9� May react exothermically with reducing agents to release hydrogen gas. Cyclohexene Flinn Scientific, Inc. P.O. Cyclohexene (8 g, 0.097 mole) is added to a mixture of 105 g of 98–100% formic acid and 13 g (0.115 mole) of 30% hydrogen peroxide contained in a 250-ml flask fitted with a reflux condenser. 3 Effective date : 12.20.2014 Page 2 of 7 Cyclohexene Created by Global Safety Management, Inc. -Tel: 1-813-435-5161 - www.gsmsds.com Read label before use Keep container tightly closed Avoid release to the environment Do not eat, drink or smoke when using this product Cyclohexene is a hydrocarbon with the formula C 6 H 10. It is an intermediate in various industrial processes. Material Safety Data Sheet Page 1 of 2 ... Cyclohexene MSDS # 243.00 Section 1: Product and Company Identification Cyclohexene Synonyms/General Names: 1,2,3,4-tetrahydrobenzene Product Use: For educational use only Manufacturer: Columbus Chemical Industries, Inc., Columbus, WI 53925. AI3-19937. This (M)SDS is a generic document with no country specific information included. Search results for 1-methyl cyclohexene at Sigma-Aldrich. endobj Articles of 2-Methylcyclohexanol are included as well. . endobj ENEC0620 - CYCLOHEXENE CYCLOHEXENE Safety Data Sheet ENEC0620 Date of issue: 08/29/2016 Version: 1.0 08/29/2016 EN (English US) SDS ID: ENEC0620 Page 1 SECTION 1: Identification of the substance/mixture and of the company/undertaking Incompatibl Cyclohexene is used as a solvent. 3 Effective date : 12.20.2014 Page 2 of 8 Cyclohexane Created by Global Safety Management, Inc. -Tel: 1-813-435-5161 - www.gsmsds.com Precautionary statements: If medical advice is needed, have product container or label at hand Keep out of reach of children Read label before use with 10% sodium carbonate solution (10 mL).